In contrast, the yields of COL over Pt/Co(OH) 2 and Pt/Al(OH) 3 were only 73 % and 34 % respectively. Characterizations including Raman, O-XAFS, XPS revealed that the Co 2+ −O 2− −Al 3+ structure in CoAl-LDHs contributed to strengthened metal-support interactions, and resulted in electron-rich and geometric decoration Pt δ− sites.
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Get QuotePt/CoAl 2 O 4 catalysts with small amounts of Pt (0.3 and 1 wt.%) were prepared by wet impregnation of platinum on cobalt aluminate (mole ratio Co/Al = 0.625). These catalysts were compared with monometallic Pt/alumina and cobalt aluminate counterparts. The physicochemical characteristics of the obtained materials were …
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Get QuoteThe hydrogenation over Pt/CoAl-MMO and Pt/ CoAl-LDH catalysts affords COL with 75.9 and 74.2% selectivity with a reaction conversion of 93.1 and 94.3%, respectively.
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Get QuoteIn contrast, the yields of COL over Pt/Co(OH) 2 and Pt/Al(OH) 3 were only 73 % and 34 % respectively. Characterizations including Raman, O-XAFS, XPS revealed that the Co 2+ −O 2− −Al 3+ …
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Get QuoteIn this work, a Pt/CoAl‐LDHs catalyst was prepared for hydrogenation of CAL, showing outstanding intrinsic activity (TOF as high as 4.93s‐1) and finally achieving 93.6% selectivity at 95.4% ...
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